|
|
S-adenosyl-L-methionine + apigenin <=> H+ + S-adenosyl-L-homocysteine + acacetin
|
2.1.1.155
kaempferol 4'-O-methyltransferase
2.1.1.231
flavonoid 4'-O-methyltransferase
2.1.1.75
apigenin 4'-O-methyltransferase
|
–
–
–
|
MK
|
| |
BRENDA:
BR43917
KEGG:
R03571
MetaCyc:
APIGENIN-4-O-METHYLTRANSFERASE-RXN
SABIO-RK:
3354
|
|
|
|
S-adenosyl-L-methionine + apigenin <=> S-adenosyl-L-homocysteine + genkwanin
|
2.1.1
2.1.1.153
vitexin 2''-O-rhamnoside 7-O-methyltransferase
2.1.1.B74
|
–
–
–
|
M
|
| |
BRENDA:
BR49707
MetaCyc:
RXN-14661
|
|
|
|
UDP-glucose + apigenin <=> UDP + apigenin_7-O-glucoside
|
2.4.1.170
isoflavone 7-O-glucosyltransferase
2.4.1.185
flavanone 7-O-beta-glucosyltransferase
2.4.1.237
flavonol 7-O-beta-glucosyltransferase
2.4.1.81
flavone 7-O-beta-glucosyltransferase
|
–
–
–
–
|
MK
|
| |
BRENDA:
BS322280
KEGG:
R03574
MetaCyc:
RXN-5021
|
|
|
|
naringenin + 2-oxoglutarate + O2 <=> apigenin + succinate + CO2 + H2O + H+
|
1.14.20.4
anthocyanidin synthase
1.14.20.5
flavone synthase I
|
–
–
|
MK
|
| |
BRENDA:
BS371268
KEGG:
R02445
MetaCyc:
RXN-7686
|
|
|
|
apigenin + reduced_flavodoxin + O2 <=> luteolin + flavin + H2O
|
1.14.14.81
flavanoid 3',5'-hydroxylase
1.14.14.82
flavonoid 3'-monooxygenase
|
–
–
|
K
|
| |
BRENDA:
BS288545
KEGG:
R06537
|
|
|
|
naringenin + reduced_flavodoxin + O2 <=> apigenin + flavin + 2 H2O
|
1.14.19.76
flavone synthase II
|
–
|
K
|
| |
BRENDA:
BS446316
KEGG:
R12278
|
|
|
|
apigenin_7-O-glucoside + H2O <=> apigenin + beta-D-glucose
|
3.2.1.161
beta-apiosyl-beta-glucosidase
3.2.1.21
beta-glucosidase
|
–
–
|
|
| |
BRENDA:
BS370866
SABIO-RK:
12345
|
|
|
|
apigenin + 2 NADPH + 2 H+ + O2 <=> 2,5,7,4'-tetrahydroxyisoflavanone + 2 NADP+ + H2O
|
not assigned
|
–
|
|
| |
KEGG:
R06792
|
|
|
|
apigenin <=> vitexin
|
not assigned
|
–
|
K
|
| |
KEGG:
R06822
|
|
|
|
apigenin <=> isovitexin
|
not assigned
|
–
|
K
|
| |
KEGG:
R06825
|
|
|
|
naringenin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> apigenin + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+
|
1.14.19.76
flavone synthase II
|
–
|
M
|
| |
MetaCyc:
RXN-7650
|
|
|
|
apigenin + reduced_[NADPH-hemoprotein_reductase] + H+ + O2 <=> 2,5,7,4'-tetrahydroxyisoflavanone + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.87
2-hydroxyisoflavanone synthase
|
–
|
M
|
| |
MetaCyc:
RXN-7750
|
|
|
|
UDP-glucose + apigenin <=> vitexin + UDP + H+
|
2.4.1
|
–
|
M
|
| |
MetaCyc:
RXN-9704
|
|
|
|
apigenin + reduced_[NADPH-hemoprotein_reductase] + O2 <=> luteolin + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.82
flavonoid 3'-monooxygenase
|
–
|
M
|
| |
MetaCyc:
RXN66-587
|
|
|
|
dimethylallyl_diphosphate + apigenin <=> diphosphate + 3''-C-dimethylallyl_apigenin
|
2.5.1.111
4-hydroxyphenylpyruvate 3-dimethylallyltransferase
|
–
|
|
| |
BRENDA:
BS423343
|
|
|
|
naringenin + 2-oxoglutarate + O2 <=> (2R,3S)-cis-dihydrokaempferol + (+)-dihydrokaempferol + apigenin + kaempferol + succinate + CO2 + H2O
|
1.14.20.6
flavonol synthase
|
–
|
|
| |
BRENDA:
BS371265
|
|
|
|
naringenin + 2-oxoglutarate + O2 <=> apigenin + (+)-dihydrokaempferol + succinate + CO2 + 2 H2O
|
1.14.20.4
anthocyanidin synthase
|
–
|
|
| |
BRENDA:
BS443790
|
|
|
|
naringenin + 2-oxoglutarate + O2 <=> apigenin + 2-hydroxynaringenin + succinate + CO2 + H2O
|
1.14.20.5
flavone synthase I
|
–
|
|
| |
BRENDA:
BS441756
|
|
|
|
(2R)-naringenin + 2-oxoglutarate + O2 <=> apigenin + succinate + CO2 + H2O
|
1.14.20.4
anthocyanidin synthase
1.14.20.5
flavone synthase I
|
–
–
|
|
| |
BRENDA:
BS395070
|
|
|
|
apigenin + reduced_flavodoxin + O2 <=> 5,7,3'',4'',5''-pentahydroxyflavone + flavin + H2O
|
1.14.14.81
flavanoid 3',5'-hydroxylase
|
–
|
|
| |
BRENDA:
BS387875
|
|
|
|
apigenin + reduced_flavodoxin + O2 <=> 3'',8-dihydroxyapigenin + flavin + H2O
|
1.14.14.1
unspecific monooxygenase
|
–
|
|
| |
BRENDA:
BS443058
|
|
|
|
UDP-glucuronate + apigenin <=> UDP + apigenin_7-O-glucuronide
|
2.4.1.17
glucuronosyltransferase
2.4.1.189
luteolin 7-O-glucuronosyltransferase
|
–
–
|
|
| |
BRENDA:
BS322285
|
|
|
|
apigenin + UDP-glucuronate <=> UDP + apigenin_O-glucuronide
|
2.4.1.17
glucuronosyltransferase
|
–
|
|
| |
BRENDA:
BS322245
|
|
|
|
S-adenosyl-L-methionine + apigenin <=> S-adenosyl-L-homocysteine + genkwanin + 5-hydroxy-7,4''-dimethoxyflavone
|
2.1.1.B75
|
–
|
|
| |
BRENDA:
BS456412
|
|
|
|
UDP-glucose + apigenin <=> UDP + 4'',7-O-beta-D-diglucosyl-apigenin
|
2.4.1.81
flavone 7-O-beta-glucosyltransferase
|
–
|
|
| |
BRENDA:
BS435956
|
|
|
|
UDP-glucose + apigenin <=> UDP + Luteolin_7-O-glucoside
|
2.4.1.81
flavone 7-O-beta-glucosyltransferase
|
–
|
|
| |
BRENDA:
BS322988
|
|
|
|
UDP-glucose + apigenin <=> UDP + apigenin_3-O-glucoside
|
2.4.1.91
flavonol 3-O-glucosyltransferase
|
–
|
|
| |
BRENDA:
BS323101
|
|
|
|
UDP-glucose + apigenin <=> UDP + kaempferol_3-O-glucoside
|
2.4.1.91
flavonol 3-O-glucosyltransferase
|
–
|
|
| |
BRENDA:
BS435959
|
|
|
|
UDP-glucose + apigenin <=> UDP + 4''-O-beta-D-glucosyl-apigenin
|
2.4.1.81
flavone 7-O-beta-glucosyltransferase
|
–
|
|
| |
BRENDA:
BS435957
|
|
|
|
adenosine_3''-phosphate_5''-phosphosulfate + apigenin <=> adenosine_3'',5''-bisphosphate + apigenin_7-sulfate
|
2.8.2.28
quercetin-3,3'-bissulfate 7-sulfotransferase
|
–
|
|
| |
BRENDA:
BS387786
|
|
|
|
S-adenosyl-L-methionine + apigenin <=> S-adenosyl-L-homocysteine_+genkwanin
|
2.1.1.B74
|
–
|
|
| |
BRENDA:
BS456413
|
|
|
|
apigenin_7-O-glucoside + H2O <=> apigenin + D-glucose
|
3.2.1.206
oleuropein beta-glucosidase
|
–
|
|
| |
BRENDA:
BS439135
|
|
